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• W2600971857 endingPage "e364" @default.
• W2600971857 startingPage "e364" @default.
• W2600971857 abstract "The discovery of unprecedented, non-native phases of transition metal oxides is a fascinating theme in materials chemistry, including the development of new synthetic strategies with excellent size- and phase-selectivity, and elucidation of their unique physicochemical properties. Most of the first-row transition metal monoxides, such as MnO, FeO, CoO and NiO, are known to exist in a cubic phase, but only ZnO adopts a hexagonal structure. This review summarizes recent results on the syntheses and characterization of the non-native phases of h-CoO, h-MnO and c-ZnO transition metal monoxides, compared to their native phases. The investigation of the size- and phase-selective synthetic methods, formation mechanism and unique physicochemical properties of non-native transition metal monoxides would have an enormous impact on materials chemistry and open a promising avenue for magnetic, electronic and spintronic applications. Forcing transition metal monoxides to crystallize into non-native nanostructures can benefit spintronic and battery applications. Monoxides of transition metals such as cobalt, manganese and zinc monoxides (CoO, MnO, ZnO) are ideal for verifying relationships between magnetic spin and structural environment because they adopt only hexagonal and cubic crystal phases. Joon T. Park from KAIST and co-workers have reviewed strategies to produce CoO, MnO and ZnO nanoparticles with both types of crystal phases — even when the crystal packing is energetically unfavorable. Using approaches such as molecular capping agents, synthetic template, thermal decomposition and pressure-induced transformations, researchers have found ways to control synthetic reactions using kinetics instead of thermodynamics. The resulting nanomaterials, with shapes including pyramids, rods and hollow parallelepipeds, have intriguing magnetic features useful for spin-related information processing and piezoelectric energy generation. This review summarizes recent results on the syntheses and characterization of the non-native phases of h-CoO, h-MnO and c-ZnO transition metal monoxides compared to their native phases. The investigation of the size- and phase-selective synthetic methods, formation mechanism and unique physicochemical properties of non-native transition metal monoxides would have an enormous impact on materials chemistry and open a promising avenue for magnetic, electronic, and spintronic applications." @default.
• W2600971857 created "2017-04-07" @default.
• W2600971857 creator A5025415011 @default.
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• W2600971857 creator A5088776131 @default.
• W2600971857 date "2017-03-01" @default.
• W2600971857 modified "2023-09-26" @default.
• W2600971857 title "Non-native transition metal monoxide nanostructures: unique physicochemical properties and phase transformations of CoO, MnO and ZnO" @default.
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• W2600971857 doi "https://doi.org/10.1038/am.2017.38" @default.
• W2600971857 hasPublicationYear "2017" @default.
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