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• W2601205065 abstract "Reductive dechlorination of carbon tetrachloride (CT) was investigated during bioreduction of iron-containing clay mineral (i.e., nontronite) by iron-reducing bacteria (Shewanella putrefaciens CN32 (CN32)). In the absence of CT, the production of Fe(II) significantly increased in nontronite suspension with CN32 in 124 d (11.1% of Fe(III) reduction), resulting in formation of new secondary Fe(II) mineral phase (i.e., vivianite (FeII3(PO4)2·8H2O)). In the presence of CT, an acceleration of CT dechlorination was observed after 13 d and it reached almost 68% of removal efficiency at 32 d in nontronite suspension with CN32, which was 1.8 times higher than that by CN32 alone (37%). Significant amounts of formate (30.1%) and CO (2.4%) were measured during the CT dechlorination in the nontronite suspension with CN32. Results obtained from Fe(II) measurement and X-ray diffraction (XRD) showed the acceleration of Fe(II) production after 13 d and the formation of vivianite in the range of 13-25 d, suggesting that the biogenic vivianite enhanced the CT dechlorination in this study. Experimental results from batch kinetic tests, Fe(II) measurements, XRD analysis, and by-product study suggested that the formation of vivianite can play a crucial role for the enhanced reductive dechlorination of CT in phosphorous enriched subsurface environments with iron-containing clay minerals." @default.
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• W2601205065 date "2017-07-01" @default.
• W2601205065 modified "2023-09-27" @default.
• W2601205065 title "Reductive dechlorination of carbon tetrachloride by bioreduction of nontronite" @default.
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• W2601205065 doi "https://doi.org/10.1016/j.jhazmat.2017.03.066" @default.
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