Matches in SemOpenAlex for { <https://semopenalex.org/work/W2601366915> ?p ?o ?g. }
- W2601366915 endingPage "2248" @default.
- W2601366915 startingPage "2242" @default.
- W2601366915 abstract "An efficient solvent-free nickel-catalyzed method for C−H bond arylation of arenes and indoles has been developed, which proceeds expeditiously through chelation assistance. The reaction is highly selective for mono-arylation and tolerates sensitive and structurally diverse functionalities, such as halides, ethers, amines, indole, pyrrole and carbazole. This reaction represents the first example of a nickel-catalyzed C−H arylation by monochelate assistance and symbolizes a rare precedent in solvent-free C−H arylation. Mechanistic investigations by various controlled reactions, kinetic studies, and deuterium labeling experiments suggest that the arylation follows a single electron transfer (SET) pathway involving the turnover-limiting C−H nickelation process." @default.
- W2601366915 created "2017-04-07" @default.
- W2601366915 creator A5001764002 @default.
- W2601366915 creator A5056677851 @default.
- W2601366915 creator A5061124067 @default.
- W2601366915 date "2017-04-18" @default.
- W2601366915 modified "2023-10-14" @default.
- W2601366915 title "Expeditious and Solvent-Free Nickel-Catalyzed C−H Arylation of Arenes and Indoles" @default.
- W2601366915 cites W1793575896 @default.
- W2601366915 cites W1878527273 @default.
- W2601366915 cites W1918647910 @default.
- W2601366915 cites W1929016131 @default.
- W2601366915 cites W1956858148 @default.
- W2601366915 cites W1963800229 @default.
- W2601366915 cites W1970660769 @default.
- W2601366915 cites W1972577346 @default.
- W2601366915 cites W1974115964 @default.
- W2601366915 cites W1977119201 @default.
- W2601366915 cites W1979259658 @default.
- W2601366915 cites W1981390016 @default.
- W2601366915 cites W1982874695 @default.
- W2601366915 cites W1985733865 @default.
- W2601366915 cites W1989688131 @default.
- W2601366915 cites W1996848590 @default.
- W2601366915 cites W2004971800 @default.
- W2601366915 cites W2009012040 @default.
- W2601366915 cites W2011079714 @default.
- W2601366915 cites W2014616474 @default.
- W2601366915 cites W2017860035 @default.
- W2601366915 cites W2019005049 @default.
- W2601366915 cites W2024983608 @default.
- W2601366915 cites W2026374696 @default.
- W2601366915 cites W2032731092 @default.
- W2601366915 cites W2034223040 @default.
- W2601366915 cites W2036044855 @default.
- W2601366915 cites W2036221307 @default.
- W2601366915 cites W2038974680 @default.
- W2601366915 cites W2042390516 @default.
- W2601366915 cites W2048420033 @default.
- W2601366915 cites W2050573893 @default.
- W2601366915 cites W2050791488 @default.
- W2601366915 cites W2052602206 @default.
- W2601366915 cites W2057086900 @default.
- W2601366915 cites W2058091693 @default.
- W2601366915 cites W2058476328 @default.
- W2601366915 cites W2060296131 @default.
- W2601366915 cites W2066309940 @default.
- W2601366915 cites W2072243238 @default.
- W2601366915 cites W2072356342 @default.
- W2601366915 cites W2077657121 @default.
- W2601366915 cites W2082792123 @default.
- W2601366915 cites W2087133716 @default.
- W2601366915 cites W2088846288 @default.
- W2601366915 cites W2092137385 @default.
- W2601366915 cites W2095874853 @default.
- W2601366915 cites W2097186155 @default.
- W2601366915 cites W2098665439 @default.
- W2601366915 cites W2108723745 @default.
- W2601366915 cites W2109932330 @default.
- W2601366915 cites W2111944828 @default.
- W2601366915 cites W2114514252 @default.
- W2601366915 cites W2118360399 @default.
- W2601366915 cites W2119004319 @default.
- W2601366915 cites W2119309259 @default.
- W2601366915 cites W2123365931 @default.
- W2601366915 cites W2125014016 @default.
- W2601366915 cites W2125663031 @default.
- W2601366915 cites W2126576558 @default.
- W2601366915 cites W2127973843 @default.
- W2601366915 cites W2127983660 @default.
- W2601366915 cites W2133275647 @default.
- W2601366915 cites W2133542441 @default.
- W2601366915 cites W2139287008 @default.
- W2601366915 cites W2141215178 @default.
- W2601366915 cites W2148857742 @default.
- W2601366915 cites W2149775334 @default.
- W2601366915 cites W2149953671 @default.
- W2601366915 cites W2150928100 @default.
- W2601366915 cites W2157266487 @default.
- W2601366915 cites W2157398043 @default.
- W2601366915 cites W2165822455 @default.
- W2601366915 cites W2167967887 @default.
- W2601366915 cites W2206002746 @default.
- W2601366915 cites W2285749062 @default.
- W2601366915 cites W2308509085 @default.
- W2601366915 cites W2314103148 @default.
- W2601366915 cites W2314934082 @default.
- W2601366915 cites W2320411889 @default.
- W2601366915 cites W2321928492 @default.
- W2601366915 cites W2323972015 @default.
- W2601366915 cites W2323997881 @default.
- W2601366915 cites W2325698018 @default.
- W2601366915 cites W2326037131 @default.
- W2601366915 cites W2327227881 @default.
- W2601366915 cites W2328190216 @default.
- W2601366915 cites W2328672360 @default.
- W2601366915 cites W2329076747 @default.
- W2601366915 cites W2331297548 @default.