FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2602125921> ?p ?o ?g. }

• W2602125921 endingPage "14" @default.
• W2602125921 startingPage "8" @default.
• W2602125921 abstract "Chloroacetanilide herbicides are widely used pesticides in agriculture, resulting in contamination of ground and surface waters. Among the methods studied to enhance their degradation rate, reductive dechlorination is proposed. A [Co(bpy(CH2OH)2)2]2+ complex allowing electrocatalytic reduction of chloroacetanilide herbicides is covalently immobilized on a 3D porous electrode previously functionalized by electrografting methods. Bulk electrolyses performed on alachlor in a flow electrochemical cell show the high catalytic activity of the Co complex, leading to a total reduction of the substrate and a good selectivity toward the formation of the dechlorinated derivative. Interestingly, when it is immobilized, the catalyst is more stable than in solution as shown by the turnover number of more than 360 compared with a value of 4 in solution. Biodegradability on 5 days did not show any improvement compared with the starting material, highlighting that even if chlorine atoms that are often responsible for the toxicity of a molecule are removed, the substrate can still have a biorecalcitrant behaviour. The main by-product, deschloroalachlor, was identified and was found to be not biodegradable accounting for this recalcitrance." @default.
• W2602125921 created "2017-04-07" @default.
• W2602125921 creator A5001114812 @default.
• W2602125921 creator A5022868858 @default.
• W2602125921 creator A5043950054 @default.
• W2602125921 creator A5044752255 @default.
• W2602125921 creator A5069445884 @default.
• W2602125921 creator A5073130452 @default.
• W2602125921 creator A5087527140 @default.
• W2602125921 date "2017-05-01" @default.
• W2602125921 modified "2023-10-10" @default.
• W2602125921 title "Reductive dechlorination of a chloroacetanilide herbicide in water by a Co complex-supported catalyst" @default.
• W2602125921 cites W1963774129 @default.
• W2602125921 cites W1964944062 @default.
• W2602125921 cites W1969370328 @default.
• W2602125921 cites W1971036218 @default.
• W2602125921 cites W1976474321 @default.
• W2602125921 cites W1976816020 @default.
• W2602125921 cites W1982419023 @default.
• W2602125921 cites W1988364880 @default.
• W2602125921 cites W1991023995 @default.
• W2602125921 cites W1993634099 @default.
• W2602125921 cites W1994256910 @default.
• W2602125921 cites W1998621809 @default.
• W2602125921 cites W2000504066 @default.
• W2602125921 cites W2001064675 @default.
• W2602125921 cites W2001184832 @default.
• W2602125921 cites W2001614012 @default.
• W2602125921 cites W2007354986 @default.
• W2602125921 cites W2009327494 @default.
• W2602125921 cites W2010914962 @default.
• W2602125921 cites W2017305437 @default.
• W2602125921 cites W2019220922 @default.
• W2602125921 cites W2019563169 @default.
• W2602125921 cites W2021932057 @default.
• W2602125921 cites W2023446567 @default.
• W2602125921 cites W2027881290 @default.
• W2602125921 cites W2031172272 @default.
• W2602125921 cites W2034469905 @default.
• W2602125921 cites W2035487504 @default.
• W2602125921 cites W2037847030 @default.
• W2602125921 cites W2040828365 @default.
• W2602125921 cites W2041798693 @default.
• W2602125921 cites W2042199326 @default.
• W2602125921 cites W2046495564 @default.
• W2602125921 cites W2048014635 @default.
• W2602125921 cites W2048190588 @default.
• W2602125921 cites W2049897699 @default.
• W2602125921 cites W2050448132 @default.
• W2602125921 cites W2053244395 @default.
• W2602125921 cites W2055919613 @default.
• W2602125921 cites W2059823025 @default.
• W2602125921 cites W2063699921 @default.
• W2602125921 cites W2067059426 @default.
• W2602125921 cites W2067437593 @default.
• W2602125921 cites W2069826586 @default.
• W2602125921 cites W2070208395 @default.
• W2602125921 cites W2076075536 @default.
• W2602125921 cites W2078101726 @default.
• W2602125921 cites W2080194297 @default.
• W2602125921 cites W2084397450 @default.
• W2602125921 cites W2086720107 @default.
• W2602125921 cites W2090682966 @default.
• W2602125921 cites W2090865123 @default.
• W2602125921 cites W2103094048 @default.
• W2602125921 cites W2121938804 @default.
• W2602125921 cites W2130708717 @default.
• W2602125921 cites W2154625037 @default.
• W2602125921 cites W2343237507 @default.
• W2602125921 cites W2415363010 @default.
• W2602125921 cites W4241565345 @default.
• W2602125921 cites W4241743996 @default.
• W2602125921 doi "https://doi.org/10.1016/j.mcat.2017.01.021" @default.
• W2602125921 hasPublicationYear "2017" @default.
• W2602125921 type Work @default.
• W2602125921 sameAs 2602125921 @default.
• W2602125921 citedByCount "20" @default.
• W2602125921 countsByYear W26021259212017 @default.
• W2602125921 countsByYear W26021259212018 @default.
• W2602125921 countsByYear W26021259212019 @default.
• W2602125921 countsByYear W26021259212020 @default.
• W2602125921 countsByYear W26021259212021 @default.
• W2602125921 countsByYear W26021259212022 @default.
• W2602125921 countsByYear W26021259212023 @default.
• W2602125921 crossrefType "journal-article" @default.
• W2602125921 hasAuthorship W2602125921A5001114812 @default.
• W2602125921 hasAuthorship W2602125921A5022868858 @default.
• W2602125921 hasAuthorship W2602125921A5043950054 @default.
• W2602125921 hasAuthorship W2602125921A5044752255 @default.
• W2602125921 hasAuthorship W2602125921A5069445884 @default.
• W2602125921 hasAuthorship W2602125921A5073130452 @default.
• W2602125921 hasAuthorship W2602125921A5087527140 @default.
• W2602125921 hasConcept C111368507 @default.
• W2602125921 hasConcept C118792377 @default.
• W2602125921 hasConcept C127313418 @default.
• W2602125921 hasConcept C147789679 @default.
• W2602125921 hasConcept C157021035 @default.
• W2602125921 hasConcept C161176658 @default.

• next