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- W2602319321 endingPage "3989" @default.
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- W2602319321 abstract "The rearrangement of allylic trichloroacetimidates is a well-known transformation, but the corresponding rearrangement of benzylic trichloroacetimidates has not been explored as a method for the synthesis of benzylic amines. Conditions that provide the trichloroacetamide product from a benzylic trichloroacetimidate in high yield have been developed. Methods were also investigated to transform the trichloroacetamide product directly into the corresponding amine, carbamate, and urea. A cationic mechanism for the rearrangement is implicated by the available data." @default.
- W2602319321 created "2017-04-07" @default.
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- W2602319321 date "2017-03-27" @default.
- W2602319321 modified "2023-09-25" @default.
- W2602319321 title "Rearrangement of Benzylic Trichloroacetimidates to Benzylic Trichloroacetamides" @default.
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- W2602319321 doi "https://doi.org/10.1021/acs.joc.7b00245" @default.
- W2602319321 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5458781" @default.
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