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- W2602490860 abstract "The adsorption of iodine on National Carbon type TSX graphite was studied at 100, 200, 500 and 800°C, over the pressure range 0.01–15 mm Hg, using a tracer technique. Above 200°C iodine was chemisorbed on a small fraction of the graphite surface. At 100°C the iodine was held on the graphite by both chemisorption and physical adsorption. The surface area of the graphite, determined from the 100°C iodine adsorption isotherm using the B.E.T. theory, was found to be in good agreement with surface area values obtained from nitrogen isotherms at −195°C. No relation was found between the amounts of iodine adsorbed on various samples and their surface area, at concentrations below one monolayer. The adsorption of iodine was enhanced by high temperature outgassing (2000°C) and contact with water vapor at 900°C. A small fraction of the iodine adsorbed at 25 and 100°C could not be removed from the graphite by heating in vacuo at 950°C. The amount of iodine irreversibly adsorbed at 25°C, in saturated iodine vapor, was approximately proportional to the reversible iodine adsorption at higher temperatures." @default.
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- W2602490860 date "1964-08-01" @default.
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- W2602490860 title "The behavior of iodine in graphite" @default.
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