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• W2602511894 abstract "Abstract A straightforward synthesis of C ‐nor‐ D ‐homo steroids starting from (+)‐Wieland–Miescher ketone is reported. This convergent synthetic strategy utilizes a scalable diastereoselective Nazarov cyclization of functionalized chiral aryl vinyl ketones, allowing for further functionalization. The ability to conduct this key transformation on a multi‐gram scale paves the way for the synthesis of a variety of completely new C ‐nor‐ D ‐homo steroids, without the need of a classic steran steroid rearrangement or achiral linear reaction sequences." @default.
• W2602511894 created "2017-04-07" @default.
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• W2602511894 date "2017-03-27" @default.
• W2602511894 modified "2023-10-15" @default.
• W2602511894 title "Lewis Acid Mediated Nazarov Cyclization as a Convergent and Enantioselective Entry to <i>C</i>‐nor‐<i>D</i>‐homo‐Steroids" @default.
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• W2602511894 doi "https://doi.org/10.1002/chem.201701008" @default.
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