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- W2602771520 abstract "Abstract Organoselenium‐catalyzed oxidative deoximations afforded ketones and aldehydes under mild conditions. The reactions employ hydrogen peroxide and air as clean oxidants and lead to a waste‐free and metal‐free deprotection protocol for carbonyl protection strategies as well as the green synthesis of ketones and aldehydes. The mechanisms of this interesting organoselenium‐catalyzed reaction have been investigated by control experiments as well as the selenium 77 nuclear magnetic resonance ( 77 Se NMR) tests. This novel reaction largely expands the application scope of organoselenium catalysis. magnified image" @default.
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- W2602771520 date "2017-03-15" @default.
- W2602771520 modified "2023-10-14" @default.
- W2602771520 title "Green and Practical Oxidative Deoximation of Oximes to Ketones or Aldehydes with Hydrogen Peroxide/Air by Organoselenium Catalysis" @default.
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- W2602771520 doi "https://doi.org/10.1002/adsc.201601353" @default.
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