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- W2603245071 abstract "In recent years it has become clear that the interfacial layer formed around nanoparticles in polymer nanocomposites (PNCs) is critical for controlling their macroscopic properties. The interfacial layer occupies a significant volume fraction of the polymer matrix in PNCs and creates strong intrinsic heterogeneity in their structure and dynamics. Here, we focus on analysis of the structure and dynamics of the interfacial region in model PNCs with well-dispersed, spherical nanoparticles with attractive interactions. First, we discuss several experimental techniques that provide structural and dynamic information on the interfacial region in PNCs. Then, we discuss the role of various microscopic parameters in controlling structure and dynamics of the interfacial layer. The analysis presented emphasizes the importance of the polymer-nanoparticle interactions for the slowing down dynamics in the interfacial region, while the thickness of the interfacial layer appears to be dependent on chain rigidity, and has been shown to increase with cooling upon approaching the glass transition. Aside from chain rigidity and polymer-nanoparticle interactions, the interfacial layer properties are also affected by the molecular weight of the polymer and the size of the nanoparticles. In the final part of this focus article, we emphasize the important challenges in the field of polymer nanocomposites and a potential analogy with the behavior observed in thin films." @default.
- W2603245071 created "2017-04-07" @default.
- W2603245071 creator A5005620618 @default.
- W2603245071 creator A5006376934 @default.
- W2603245071 creator A5042083426 @default.
- W2603245071 creator A5045021143 @default.
- W2603245071 creator A5046168058 @default.
- W2603245071 creator A5051581536 @default.
- W2603245071 date "2017-03-30" @default.
- W2603245071 modified "2023-10-01" @default.
- W2603245071 title "Focus: Structure and dynamics of the interfacial layer in polymer nanocomposites with attractive interactions" @default.
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