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• W2603816423 startingPage "1600596" @default.
• W2603816423 abstract "Semi-interpenetrating polymer network (semi-IPN) strategy is employed to fabricate uniform microspheres with temperature and pH dual-responsive behavior, which is composed of poly(N-isopropylacrylamide) and poly(acrylic acid) in the presence of N,N-methylenebisacrylamide (MBA) as the cross-linker. The influences of MBA amount (M-m) on the structures and properties of the microspheres are investigated in terms of particle size, surface morphology, pH sensitivity, and thermo-sensitivity with low critical solution temperature in the range M-m = 2.5-15%. Additionally, functional group distributions in the microspheres are probed by titration and employing the Henderson-Hasselbalch equation. The results show that all the properties strongly change depending on M-m. Based on transmission electron microscopy and confocal laser scanning microscopy measurements, and these properties, the M-m-induced changes in the structures of the semi-IPN microspheres are discussed." @default.
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• W2603816423 date "2017-03-21" @default.
• W2603816423 modified "2023-10-09" @default.
• W2603816423 title "Effects of Cross-Link Density on Structures and Properties of Dual-Sensitive Semi-Interpenetrating Polymer Networks Hydrogel Microspheres" @default.
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• W2603816423 doi "https://doi.org/10.1002/macp.201600596" @default.
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