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• W2604184679 endingPage "5040" @default.
• W2604184679 startingPage "5034" @default.
• W2604184679 abstract "A binuclear Cu(II) complex, 1, [Cu2(L-)2(OAc)](OAc) of imidazole-based ligand LH {LH = 2-(bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methyl)phenol} was synthesized and characterized spectroscopically and structurally. Addition of an equivalent amount of nitric oxide (NO) by a gastight syringe to the acetonitrile:methanol (5:1, v/v) solution of complex 1 at room temperature resulted in the reduction of Cu(II) center to Cu(I) with concomitant C-nitrosation of the ligand. Spectroscopic characterization of the resulting Cu(I) complex (1a) of the C-nitrosylated ligand, L' {L' = 2-(bis(2-ethyl-5-methyl-1H-imidazol-4-yl)methyl)-4-nitroso-phenol} has been done. The Cu(I) complex, 1a, further reacted with NO to result in the corresponding N-nitrosohydroxylaminato complex, 2, [Cu2(L-ONNO)2](OAc)2 through the formation of a Cu(I)-nitrosyl intermediate. A small fraction of the nitrosyl intermediate decomposed to the corresponding Cu(II) complex 3, [Cu(L')2], and N2O in a parallel reaction." @default.
• W2604184679 created "2017-04-14" @default.
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• W2604184679 date "2017-04-07" @default.
• W2604184679 modified "2023-10-10" @default.
• W2604184679 title "Nitric Oxide Reactivity of a Cu(II) Complex of an Imidazole-Based Ligand: Aromatic C-Nitrosation Followed by the Formation of <i>N</i>-Nitrosohydroxylaminato Complex" @default.
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• W2604184679 doi "https://doi.org/10.1021/acs.inorgchem.7b00069" @default.
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