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• W2604222807 abstract "Gas hydrate is not only a potential energy resource, but also almost the biggest challenge in oil/gas flow assurance. Inorganic salts such as NaCl, KCl and CaCl2 are widely used as the thermodynamic inhibitor to reduce the risk caused by hydrate formation. However, the inhibition mechanism is still unclear. Therefore, molecular dynamic (MD) simulation was performed to study the dissociation of structure I (SI) methane hydrate in existence of inorganic salt aqueous solution on a micro-scale. The simulation results showed that, the dissociation became stagnant due to the presence of liquid film formed by the decomposed water molecules, and more inorganic ions could shorten the stagnation-time. The diffusion coefficients of ions and water molecules were the largest in KCl system. The structures of ion/H2O and H2O/H2O were the most compact in hydrate/NaCl system. The ionic ability to decompose hydrate cells followed the sequence of: Ca2+ > 2K+ > 2Cl− > 2Na+." @default.
• W2604222807 created "2017-04-14" @default.
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• W2604222807 date "2017-08-01" @default.
• W2604222807 modified "2023-10-18" @default.
• W2604222807 title "A molecular dynamic study on the dissociation mechanism of SI methane hydrate in inorganic salt aqueous solutions" @default.
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• W2604222807 doi "https://doi.org/10.1016/j.jmgm.2017.03.022" @default.
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