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• W2604313120 abstract "Intramolecular C–C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO)3 fragments. The nucleophilic CH2 group generated by the deprotonation attacks the 6 (bipy) or 2 (phen) positions of the diimines, dearomatizing the involved pyridine ring and generating new asymmetric, fac-capping tridentate ligands." @default.
• W2604313120 created "2017-04-14" @default.
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• W2604313120 date "2017-04-03" @default.
• W2604313120 modified "2023-09-26" @default.
• W2604313120 title "Interligand C–C Coupling between α-Methyl N-Heterocycles and bipy or phen at Rhenium Tricarbonyl Complexes" @default.
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• W2604313120 doi "https://doi.org/10.1021/acs.inorgchem.7b00078" @default.
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