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• W2604342436 abstract "Significance Diffusion on the surfaces of molecular glasses is observed to be greatly enhanced compared with the bulk diffusion with lower activation energies. However, the physical nature of the fast surface diffusion and its relation to the glassy dynamics remain unclear. Relaxation dynamics of these glasses can be enhanced by up to 14 orders of magnitude by reducing their film thickness below 50 nm. By investigating the relationship between surface diffusion and relaxation times of ultrathin films, we find that the fast surface diffusion remains invariant of the films’ relaxation dynamics even when the activation energy of the film becomes lower than the activation energy for the surface diffusion, indicating a complete decoupling of the relaxation dynamics and surface diffusion." @default.
• W2604342436 created "2017-04-14" @default.
• W2604342436 creator A5010776860 @default.
• W2604342436 creator A5088670364 @default.
• W2604342436 date "2017-04-03" @default.
• W2604342436 modified "2023-10-15" @default.
• W2604342436 title "Decoupling of surface diffusion and relaxation dynamics of molecular glasses" @default.
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• W2604342436 doi "https://doi.org/10.1073/pnas.1701400114" @default.
• W2604342436 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5441703" @default.
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• W2604342436 hasPublicationYear "2017" @default.
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