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- W2605187478 abstract "Nucleobases are building blocks of nucleic acids (DNA, RNA)where they are responsible for the transfer of geneticinformation. The structure and properties of nucleic acids canbe influenced by their protonation and/or their complexationwith metal ions [1]. Some structurally modified nucleobases andnucleosides exhibit physiological activity and therefore theyare used as drugs [2]. This contribution is focused on thestudy of protonation constants of adenine-like compounds. Theywere determined by means of molecular absorption spectroscopyin UV region (I = 0.15 mol.l-1 M NaCl, t = 25 degrees C) andthe experimental data were evaluated by OPIUM program. Inaddition, the temperature and ionic-strength dependence ofprotonation constants of studied ligands was used to estimatethermodynamic parameters (deltaH0, deltaS0, protonationconstant(s) for infinite dilution). In some cases, theluminescence emission spectroscopy was also employed due tosignificantly high quantum yield of some compounds. Someexamples of ligand complexation by zinc metal ion will bepresented and their importance for bioligand speciation in vivowill be discussed." @default.
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- W2605187478 date "2013-01-01" @default.
- W2605187478 modified "2023-09-26" @default.
- W2605187478 title "A solution study of chemical equilibria of physiologicallyactive nucleobases" @default.
- W2605187478 hasPublicationYear "2013" @default.
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