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- W2605428133 abstract "The interactions between anti-anxiety drug diazepam (DZM) and ionic surfactants [sodium dodecyl sulfate (SDS) and hexadecyltrimethylammonium bromide (HTAB)] in 0.57 mol% aqueous ethanol solution have been studied by employing conductivity measurements over a range of temperature [288.15 to 318.15 K in case of SDS and 298.15 to 318.15 K in case of HTAB]. From these measurements, critical micelle concentration (CMC), degree of dissociation of counter ion (α), standard free energy (ΔGmᴼ), standard enthalpy (ΔHmᴼ) and standard entropy (ΔSmᴼ) of micellization were calculated. UV–visible and fluorescence studies were carried out for DZM-surfactant complex in the pre-micellar and post-micellar region. From these studies various parameters like partition coefficient (Kx), binding constant (Kb), free energy of partition (ΔGxᴼ), free energy of binding (ΔGbᴼ) and number of drug molecules per micelle (n) were calculated. Proton (1H) NMR studies show upfield shift which indicates shielding of protons of SDS and HTAB. From UV–visible, fluorescence and 1H NMR studies it was concluded that drug molecules lie in the palisade layer or the interface of the SDS/HTAB micelles." @default.
- W2605428133 created "2017-04-28" @default.
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- W2605428133 date "2017-06-01" @default.
- W2605428133 modified "2023-09-28" @default.
- W2605428133 title "Interactions of diazepam with sodium dodecylsulfate and hexadecyl trimethyl ammonium bromide: Conductometric, UV–visible spectroscopy, fluorescence and NMR studies" @default.
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- W2605428133 doi "https://doi.org/10.1016/j.molliq.2017.04.043" @default.
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