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- W2605604188 abstract "Fluorinated nitrile imines generated in situ from the corresponding fluoral-derived hydrazonoyl bromides smoothly react with monomeric aryl/hetaryl-substituted thiochalcones yielding 2,3-dihydro-1,3,4-thiadiazoles in a chemo- and regioselective manner. The elaborated protocol can be efficiently applied starting with precursors functionalized with both electron-donating and electron-withdrawing groups located at the <i>para</i> position of the aryl ring. In contrast, the non-fluorinated nitrile imines do not enter the (3+2)-cycloaddition reactions with title thiochalcones." @default.
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- W2605604188 date "2017-04-11" @default.
- W2605604188 modified "2023-10-14" @default.
- W2605604188 title "First (3+2)-Cycloadditions of Thiochalcones as C=S Dipolarophiles: Efficient Synthesis of 1,3,4-Thiadiazoles via Reactions with Fluorinated Nitrile Imines" @default.
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- W2605604188 doi "https://doi.org/10.1055/s-0036-1588774" @default.
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