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- W2606169637 abstract "The absolute configuration of bisabolangelone has been established by an eleven step total synthesis of the corresponding TMS protected antipode starting from (R)-(+)-pulegone. Comparison of the TMS-derivatives by GC on a chiral column, allowed us to assign the absolute configuration of the synthetic compound and thus of the corresponding natural product. The latter has been confirmed by the Mosher's ester analysis of the known secondary carbinol derivative." @default.
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- W2606169637 date "2017-06-01" @default.
- W2606169637 modified "2023-09-24" @default.
- W2606169637 title "Total synthesis of TMS- ent -bisabolangelone" @default.
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- W2606169637 doi "https://doi.org/10.1016/j.tet.2017.04.042" @default.
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