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• W2606475982 abstract "Summary The interactions between phosphates, both inorganic and organic ones, and heavy metals on mineral surfaces affect their environmental fate and transport. In this research, we investigated the co‐sorption of myo ‐inositol hexakisphosphate ( IHP ) and cadmium ( C d( II )) on to haematite at various pHs in batch experiments, zeta ( ζ ) potential measurement and in situ attenuated total reflectance F ourier transform infrared ( ATR‐FTIR ) spectroscopy. In the haematite– IHP binary system, IHP formed inner‐sphere complexes on haematite in which some phosphate groups of the IHP molecule bonded with the haematite surface, and other dissociated phosphate groups were ionized. In the haematite– IHP–C d ternary system, the presence of aqueous C d( II ) increases IHP sorption and the ζ potential of haematite relative to that in the haematite– IHP binary system. The enhancement is more obvious at higher pHs , reversing the initial pH dependence of IHP sorption in the binary system. Similarly, the coexisting IHP promotes the retention of C d( II ) on haematite. The ATR‐FTIR spectroscopy indicates the formation of two structurally distinct ternary surface complexes (the H m– IHP–C d surface complex and the H m– C d– IHP–C d surface complex). Our results suggest that simultaneous sorption not only increases the sorption density of IHP and C d( II ), but also changes the surface complex configuration of IHP and Cd( II ) on haematite. Highlights The interactions between IHP and C d( II ) on haematite were investigated. The presence of C d( II ) increases IHP sorption and vice versa . IHP and C d( II ) co‐sorption is enhanced as pH increases. Two structurally distinct ternary surface complexes form on haematite surfaces." @default.
• W2606475982 created "2017-04-28" @default.
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• W2606475982 date "2017-04-12" @default.
• W2606475982 modified "2023-10-14" @default.
• W2606475982 title "Quantitative and spectroscopic investigations of the co-sorption of<i>myo</i>-inositol hexakisphosphate and cadmium(II) on to haematite" @default.
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• W2606475982 doi "https://doi.org/10.1111/ejss.12424" @default.
• W2606475982 hasPublicationYear "2017" @default.
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