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- W2606770108 endingPage "47" @default.
- W2606770108 startingPage "39" @default.
- W2606770108 abstract "Eight new fluorescent ligands (L1-L8) derived from the fused imidazo[4,5-f]-1,10-phenanthroline core, have been synthesised utilising a one-pot methodology. The ligands include two points of structural variety, allowing multiply-substituted aryl groups (including hydroxy and methoxy moieties) to be attached to the ligand core. The ligands L1-L8 are fluorescent (λem = 399–426 nm) and react with pentacarbonylbromorhenium to give coordination complexes of the form fac-[ReBr(CO)3(NˆN)] (where NˆN = L1-L8). The complexes were characterised using a variety of spectroscopic and analytical techniques, including single crystal X-ray diffraction studies on two examples. The rhenium complexes were all found to be luminescent, revealing classical 3MLCT emission at 579–587 nm in aerated solution with corresponding lifetimes in the range 149–166 ns." @default.
- W2606770108 created "2017-04-28" @default.
- W2606770108 creator A5014634951 @default.
- W2606770108 creator A5047250570 @default.
- W2606770108 creator A5054654375 @default.
- W2606770108 creator A5056742906 @default.
- W2606770108 creator A5083477448 @default.
- W2606770108 creator A5091039025 @default.
- W2606770108 date "2017-07-01" @default.
- W2606770108 modified "2023-10-16" @default.
- W2606770108 title "Synthesis and characterisation of phosphorescent rhenium(I) complexes of hydroxy- and methoxy-substituted imidazo[4,5- f ]-1,10-phenanthroline ligands" @default.
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