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• W2606810013 abstract "The first example of a diazo palladium adduct is reported. The complexes [(ArNHC−PPh2)M(η2-N2C(Ph)CO2Et)] (M=Ni, 3; M=Pd, 4; ArNHC−PPh2=3-(2,6-diisopropylphenyl)-1-[(diphenylphosphino)ethyl]imidazol-2-ylidene) were prepared by ligand exchange with styrene-coordinated precursors [(ArNHC−PPh2)M(styrene)] (M=Ni, 1; M=Pd, 2). Complex 4 was fully characterized, including X-ray analyses; this constitutes the first example of a diazo adduct compound with palladium, thereby closing the gap between Groups 8 and 10 regarding this type of compounds." @default.
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• W2606810013 date "2017-05-16" @default.
• W2606810013 modified "2023-09-30" @default.
• W2606810013 title "The Elusive Palladium-Diazo Adduct Captured: Synthesis, Isolation and Structural Characterization of [(ArNHC-PPh₂ )Pd(η² -N₂ C(Ph)CO₂ Et)]" @default.
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• W2606810013 doi "https://doi.org/10.1002/chem.201701362" @default.
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