Matches in SemOpenAlex for { <https://semopenalex.org/work/W2606901927> ?p ?o ?g. }
- W2606901927 endingPage "12695" @default.
- W2606901927 startingPage "12681" @default.
- W2606901927 abstract "Abstract The combined oxidation of hydrogen and carbon monoxide over platinum in micro-combustors at catalytic surface temperatures below 600 K was studied numerically, using a two-dimensional computational fluid dynamics (CFD) model with detailed heterogeneous and homogeneous reaction mechanisms and multicomponent transport. Simulations were performed at different surface temperatures and feed compositions to study the kinetic interplay between hydrogen and carbon monoxide. A sensitivity analysis of the heterogeneous reaction mechanism was performed to identify the rate-controlling steps. Finally, possible mechanisms for the observed behavior were discussed. It was shown that there is significant kinetic interplay between hydrogen and carbon monoxide. Carbon monoxide significantly inhibits the catalytic oxidation of hydrogen. In contrast, the presence of hydrogen was found to promote the catalytic oxidation of carbon monoxide, with the largest effect shown for the small addition of hydrogen, then this effect progressively decreases with the further increase of hydrogen concentration. Accordingly, the apparent reaction order with respect to hydrogen changes from positive to negative, then to zero. The promoting effect of hydrogen can be attributed to the carboxyl pathway, which is crucial to describe the process." @default.
- W2606901927 created "2017-04-28" @default.
- W2606901927 creator A5005950292 @default.
- W2606901927 creator A5020930762 @default.
- W2606901927 creator A5023481911 @default.
- W2606901927 creator A5029892501 @default.
- W2606901927 date "2017-04-01" @default.
- W2606901927 modified "2023-10-14" @default.
- W2606901927 title "Kinetic interplay between hydrogen and carbon monoxide in syngas-fueled catalytic micro-combustors" @default.
- W2606901927 cites W101862313 @default.
- W2606901927 cites W1066721198 @default.
- W2606901927 cites W1555037384 @default.
- W2606901927 cites W1966752759 @default.
- W2606901927 cites W1966799339 @default.
- W2606901927 cites W1967343239 @default.
- W2606901927 cites W1968004214 @default.
- W2606901927 cites W1968599821 @default.
- W2606901927 cites W1970933698 @default.
- W2606901927 cites W1971143893 @default.
- W2606901927 cites W1972864754 @default.
- W2606901927 cites W1973085334 @default.
- W2606901927 cites W1975620623 @default.
- W2606901927 cites W1984389792 @default.
- W2606901927 cites W1984580516 @default.
- W2606901927 cites W1986613769 @default.
- W2606901927 cites W1987845318 @default.
- W2606901927 cites W1990944504 @default.
- W2606901927 cites W1993523837 @default.
- W2606901927 cites W1996030617 @default.
- W2606901927 cites W1996925671 @default.
- W2606901927 cites W1997458391 @default.
- W2606901927 cites W1998552045 @default.
- W2606901927 cites W2000087485 @default.
- W2606901927 cites W2003992440 @default.
- W2606901927 cites W2006201042 @default.
- W2606901927 cites W2006401125 @default.
- W2606901927 cites W2010375408 @default.
- W2606901927 cites W2017142466 @default.
- W2606901927 cites W2019594865 @default.
- W2606901927 cites W2020020760 @default.
- W2606901927 cites W2020423707 @default.
- W2606901927 cites W2024742067 @default.
- W2606901927 cites W2025515265 @default.
- W2606901927 cites W2031525325 @default.
- W2606901927 cites W2031904903 @default.
- W2606901927 cites W2033313161 @default.
- W2606901927 cites W2034434606 @default.
- W2606901927 cites W2037338774 @default.
- W2606901927 cites W2037650338 @default.
- W2606901927 cites W2037809916 @default.
- W2606901927 cites W2037841193 @default.
- W2606901927 cites W2042389092 @default.
- W2606901927 cites W2050530924 @default.
- W2606901927 cites W2053588932 @default.
- W2606901927 cites W2056507154 @default.
- W2606901927 cites W2058637897 @default.
- W2606901927 cites W2061434539 @default.
- W2606901927 cites W2062818978 @default.
- W2606901927 cites W2063430017 @default.
- W2606901927 cites W2066480514 @default.
- W2606901927 cites W2066765759 @default.
- W2606901927 cites W2069357458 @default.
- W2606901927 cites W2070445058 @default.
- W2606901927 cites W2070688928 @default.
- W2606901927 cites W2074755293 @default.
- W2606901927 cites W2074799165 @default.
- W2606901927 cites W2075367730 @default.
- W2606901927 cites W2076421838 @default.
- W2606901927 cites W2076837194 @default.
- W2606901927 cites W2079129518 @default.
- W2606901927 cites W2081867929 @default.
- W2606901927 cites W2084373616 @default.
- W2606901927 cites W2084799464 @default.
- W2606901927 cites W2089046726 @default.
- W2606901927 cites W2089467325 @default.
- W2606901927 cites W2090949644 @default.
- W2606901927 cites W2093621821 @default.
- W2606901927 cites W2096771229 @default.
- W2606901927 cites W2133471473 @default.
- W2606901927 cites W2136733582 @default.
- W2606901927 cites W2143844135 @default.
- W2606901927 cites W2147630065 @default.
- W2606901927 cites W2153291990 @default.
- W2606901927 cites W2157275480 @default.
- W2606901927 cites W2165192867 @default.
- W2606901927 cites W2194893096 @default.
- W2606901927 cites W2210895890 @default.
- W2606901927 cites W2235712588 @default.
- W2606901927 cites W2261349251 @default.
- W2606901927 cites W2312614464 @default.
- W2606901927 cites W2322718557 @default.
- W2606901927 cites W2405127129 @default.
- W2606901927 cites W2468901697 @default.
- W2606901927 cites W2469171298 @default.
- W2606901927 cites W2471234735 @default.
- W2606901927 cites W2475625604 @default.
- W2606901927 cites W396809385 @default.
- W2606901927 cites W4232065740 @default.