FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2607015697> ?p ?o ?g. }

• W2607015697 endingPage "269" @default.
• W2607015697 startingPage "251" @default.
• W2607015697 abstract "The reaction chemistry of furanic fuels, proposed as next-generation bio-derived fuels, has been a target of recent studies. However, quantitative intermediate species profiles at low- to moderate-temperature (LMT) conditions remain scarce. The present paper reports the first systematic full speciation dataset in the temperature range 730–1170 K for three furanic fuels, 2,5-dimethylfuran (DMF), 2-methylfuran (MF), and furan, measured for different equivalence ratios under near-identical LMT conditions in a flow reactor at 1 bar. More than 35 species including reactants, intermediate species, and products were analyzed using electron ionization (EI) molecular-beam mass spectrometry (MBMS). These experimental results provided motivation to extend a previous single joint mechanism for the three furanic fuels, developed for the high-temperature regime in low-pressure premixed flames, to include the LMT oxidation chemistry. A decisive difference of the present mechanism versus all previously reported models is a more complete description of fuel radical reactions for LMT oxidation, obtained from theoretical calculations of thermodynamic properties and rate constants. The experimentally observed differences in fuel conversion behavior and species distribution between the three fuels have been compared to model predictions using the newly extended mechanism. The dependence of fuel conversion on equivalence ratio decreases significantly from DMF to furan, a behavior consistent with the different number of lateral methyl groups in the fuel structure. All three furanic fuels, especially DMF, produce several highly toxic oxygenated species including acrolein, methyl vinyl ketone, furfural, and phenol. These toxic species were found to be products of the primary reactions of these fuels, and these undesirable trends could be explained satisfactorily by the present model, pointing to some caution with regard to the potential emission spectra under LMT conditions." @default.
• W2607015697 created "2017-04-28" @default.
• W2607015697 creator A5028222619 @default.
• W2607015697 creator A5036795568 @default.
• W2607015697 creator A5036966643 @default.
• W2607015697 creator A5054545020 @default.
• W2607015697 creator A5086184098 @default.
• W2607015697 creator A5091457062 @default.
• W2607015697 date "2017-07-01" @default.
• W2607015697 modified "2023-10-11" @default.
• W2607015697 title "Comparative experimental and modeling study of the low- to moderate-temperature oxidation chemistry of 2,5-dimethylfuran, 2-methylfuran, and furan" @default.
• W2607015697 cites W1133799594 @default.
• W2607015697 cites W1965416286 @default.
• W2607015697 cites W1965725481 @default.
• W2607015697 cites W1971857577 @default.
• W2607015697 cites W1982898735 @default.
• W2607015697 cites W1992306350 @default.
• W2607015697 cites W1999114229 @default.
• W2607015697 cites W2010511943 @default.
• W2607015697 cites W2017407626 @default.
• W2607015697 cites W2018130294 @default.
• W2607015697 cites W2021337168 @default.
• W2607015697 cites W2026291154 @default.
• W2607015697 cites W2027989336 @default.
• W2607015697 cites W2029101044 @default.
• W2607015697 cites W2031453047 @default.
• W2607015697 cites W2037642592 @default.
• W2607015697 cites W2041186015 @default.
• W2607015697 cites W2045233427 @default.
• W2607015697 cites W2049693922 @default.
• W2607015697 cites W2052753704 @default.
• W2607015697 cites W2053454127 @default.
• W2607015697 cites W2063386309 @default.
• W2607015697 cites W2070222111 @default.
• W2607015697 cites W2071592915 @default.
• W2607015697 cites W2076358915 @default.
• W2607015697 cites W2077528747 @default.
• W2607015697 cites W2077850045 @default.
• W2607015697 cites W2083656933 @default.
• W2607015697 cites W2086505034 @default.
• W2607015697 cites W2091719155 @default.
• W2607015697 cites W2094139157 @default.
• W2607015697 cites W2094988546 @default.
• W2607015697 cites W2096933393 @default.
• W2607015697 cites W2102522970 @default.
• W2607015697 cites W2104582289 @default.
• W2607015697 cites W2117765118 @default.
• W2607015697 cites W2135306494 @default.
• W2607015697 cites W2165032076 @default.
• W2607015697 cites W2236378579 @default.
• W2607015697 cites W2277091242 @default.
• W2607015697 cites W2287838821 @default.
• W2607015697 cites W2316716124 @default.
• W2607015697 cites W2318467478 @default.
• W2607015697 cites W2318584283 @default.
• W2607015697 cites W2321394101 @default.
• W2607015697 cites W2326280020 @default.
• W2607015697 cites W2327431233 @default.
• W2607015697 cites W2329671506 @default.
• W2607015697 cites W2329842482 @default.
• W2607015697 cites W2332753505 @default.
• W2607015697 cites W2464314123 @default.
• W2607015697 cites W2491389137 @default.
• W2607015697 cites W2507778386 @default.
• W2607015697 cites W2529902415 @default.
• W2607015697 cites W2606323819 @default.
• W2607015697 cites W4210620494 @default.
• W2607015697 cites W4210686329 @default.
• W2607015697 doi "https://doi.org/10.1016/j.combustflame.2017.03.030" @default.
• W2607015697 hasPublicationYear "2017" @default.
• W2607015697 type Work @default.
• W2607015697 sameAs 2607015697 @default.
• W2607015697 citedByCount "61" @default.
• W2607015697 countsByYear W26070156972018 @default.
• W2607015697 countsByYear W26070156972019 @default.
• W2607015697 countsByYear W26070156972020 @default.
• W2607015697 countsByYear W26070156972021 @default.
• W2607015697 countsByYear W26070156972022 @default.
• W2607015697 countsByYear W26070156972023 @default.
• W2607015697 crossrefType "journal-article" @default.
• W2607015697 hasAuthorship W2607015697A5028222619 @default.
• W2607015697 hasAuthorship W2607015697A5036795568 @default.
• W2607015697 hasAuthorship W2607015697A5036966643 @default.
• W2607015697 hasAuthorship W2607015697A5054545020 @default.
• W2607015697 hasAuthorship W2607015697A5086184098 @default.
• W2607015697 hasAuthorship W2607015697A5091457062 @default.
• W2607015697 hasBestOaLocation W26070156973 @default.
• W2607015697 hasConcept C161790260 @default.
• W2607015697 hasConcept C178790620 @default.
• W2607015697 hasConcept C185592680 @default.
• W2607015697 hasConcept C2778659115 @default.
• W2607015697 hasConcept C2779719330 @default.
• W2607015697 hasConcept C65024703 @default.
• W2607015697 hasConceptScore W2607015697C161790260 @default.
• W2607015697 hasConceptScore W2607015697C178790620 @default.
• W2607015697 hasConceptScore W2607015697C185592680 @default.
• W2607015697 hasConceptScore W2607015697C2778659115 @default.
• W2607015697 hasConceptScore W2607015697C2779719330 @default.

• next