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- W2607029118 abstract "Hierarchical nanocomposites and multi-scale composites represent two classes of closely related material types which utilize a range of nano and microscale elements combined in an organized way to create macroscale composites with unique and, often, multifunctional properties. The critical requirement for any material to successfully incorporate nanoscale constituents is the ability to disperse the nanoscale additive with a large degree of control. The ability to realize the true benefits of nanoscale materials within larger scale matrices will usually be maximized when individual nanoparticles exist as separate entities and the massive surface area to volume ratios are exploited. Consequently, large research efforts are dedicated to the chemical modification of nanomaterial surfaces in order to control the system thermodynamic quantities in ways that can tailor the levels of dispersion. The following chapter addresses the area of hierarchical nanocomposites and multi-scale composite materials in the context of common polymeric materials used in the fabrication of polymer nanocomposites and microscale fiber reinforced polymer composites. Polymer-based materials represent some of the most widely used materials in society and have a range of applications in military and civilian industry. The ability to improve the mechanical performance, whilst imparting additional functionality, such as electrical conductivity or sensing capability, offers a range of benefits for practical applications, including material weight savings and broader and more-flexible applications. In this context, the chapter reviews current state-of-the-art research in the area of hierarchical polymer nanocomposites and examines some of the fundamental research that is developing more sophisticated methods to control nanoparticle dispersion in polymeric matrices. Some of the areas that are examined include the polymer grafting chemistry, which uses the controlled radical polymerization (CRP) methods, and block copolymer chemistry, where the ability to control nanoscale dispersion has seen widespread application in mechanical, electrical, energy storage, and sensing applications, to mention just a few areas. The hierarchical nanocomposites are closely related to multi-scaled composite materials where microscale fibers are traditionally used to reinforce polymeric materials. The development of multi-scaled composite materials sees processes that either provide a nanoscale modification of the polymeric material or the fiber preform prior to their combination into the macroscale composite material. Once again, the ability to control the interfacial chemistry in the scaled composite materials is key to successful outcomes. The hierarchical nanocomposite chemistry is, in many cases, readily transferrable into the multi-scaled composites. As the knowledge and expertise in hierarchical nanocomposite materials expands to enable the widespread application to 3D materials, the ability to apply this technology to multi-scaled composite materials will also evolve." @default.
- W2607029118 created "2017-04-28" @default.
- W2607029118 creator A5058254008 @default.
- W2607029118 date "2018-01-01" @default.
- W2607029118 modified "2023-09-27" @default.
- W2607029118 title "6.12 Hierarchical Nanocomposites/Multi-Scale Composites" @default.
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