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• W2607106567 abstract "The size of dopant-rich nanodomains was assessed in four samples of Ce 1− μ Y μ O 2− μ /2 through systematic pair distribution function (PDF) refinements. Experimental G ( r ) curves were fitted by different structural models with the aim of finding a description which balanced precise structure parameterization and reasonable number of parameters. The most reliable model was a single Y 2 O 3 -like phase, which best accommodated to the close relationship between the fluorite (CeO 2 -like) and C-type (Y 2 O 3 -like) structures. In this model, a refined cation coordinate, x (M2), measured the relative occurrence in the G ( r ) of the chemical environment of Y and Ce at any value of r . The r -value at which x (M2) vanished, i.e. at which the refined C-type cell becomes a redundant, low-symmetry description of a fluorite cell, was assumed as the size of a C-type domain. Subtle features in G ( r ) could be attributed to the fluorite or C-type phase up to ~500 Å thanks to the narrow instrumental resolution function of the ID31 beamline (now ID22) at the ESRF, which allows us to get high resolution PDF data." @default.
• W2607106567 created "2017-04-28" @default.
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• W2607106567 date "2015-05-22" @default.
• W2607106567 modified "2023-10-12" @default.
• W2607106567 title "Size and spatial correlation of defective domains in yttrium-doped CeO₂" @default.
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• W2607106567 doi "https://doi.org/10.1017/s0885715615000135" @default.
• W2607106567 hasPublicationYear "2015" @default.
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