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• W2607143513 abstract "Abstract The bifunctional 1,3-dichloro-tristannane CltBu2Sn-SntBu2-SntBu2Cl, 1, has been investigated with respect to thermolysis and nucleophilic substitution. Thermolysis of 1 leads to slow elimination of the stannylene which may be trapped by elemental sulphur, PhSSPh and 2,3-dimethylbutadiene. Reactions of 1 with the silyllithium reagent PhMe2SiLi, lead to new group 14 catenanes PhMe2Si-SntBu2-tBu2Sn-SntBu2-Cl, 9, and PhMe2Si-SntBu2-tBu2Sn-SntBu2-SntBu2-SiPhMe2, 10. Both 9 and 10 have been characterized by single crystal X-ray diffraction. Overall the new chemistry illustrates the significance of tBu2Sn: during such reactions, either loss or addition!" @default.
• W2607143513 created "2017-04-28" @default.
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• W2607143513 date "2018-04-01" @default.
• W2607143513 modified "2023-09-23" @default.
• W2607143513 title "1,3-Dichloro-1,1,2,2,3,3-hexa-tert-butyltristannane: Thermolysis involving trapping of stannylene, Bu2Sn: and reactivity with various nucleophiles" @default.
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• W2607143513 doi "https://doi.org/10.1016/j.ica.2017.03.045" @default.
• W2607143513 hasPublicationYear "2018" @default.
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