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- W2607200902 abstract "A method of storing hydrogen as metal hydride has recently attracted considerable interest and many metal hydrides have been studied for this purpose. However, most of metal hydrides are not suitable because of their low dissociation pressure. In this study, the hydride of TiCr2 base intermetallic compound is found to have a characteristic suitable for storing hydrogen. The studied alloy system is Ti1−xZrxCr2−yMny (0<x<0.4, 0<y<2.0). The alloy samples were prepared by arc melting in argon atmosphere. Crystal structure of prepared samples was confirmed to be C14-type single phase by X-ray analysis. The alloy samples reacted very actively with hydrogen to form hydride at room temperature without any activation treatment. The desorption curve of pressure-composition-temperature isotherm (P-X-T) was measured. At the composition Ti0.8Zr0.2Cr0.8Mn1.2, the dissociation pressure at 293 K was 5 atm and the partial molar enthalpy of hydrogen was determined to be −29 kJ/mol H2 from P-X-T measurement.The results of the study are summarized as follows.(1) The alloy system Ti1−xZrxCr2−yMny has C14-type crystal structure in the composition range 0<x<0.4, 0<y<2.0.(2) The alloy absorbs a large amount of hydrogen to form hydride up to the composition Ti1−xZrxCr2−yMnyH3.(3) Dissociation pressure P of this hydride system depends mainly on Zr content x and lnP is propotional to x.(4) As the Mn content increases, the plateau region increases, and the dissociation pressure does not change significantly." @default.
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- W2607200902 date "1977-01-01" @default.
- W2607200902 modified "2023-10-18" @default.
- W2607200902 title "Hydride Formation of C14-Type Ti Alloy" @default.
- W2607200902 doi "https://doi.org/10.2320/jinstmet1952.41.12_1217" @default.
- W2607200902 hasPublicationYear "1977" @default.
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