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- W2607383940 abstract "Abstract Bifunctional ZrO 2 -Fe 3 O 4 magnetic nanoparticles were synthesized and characterized, to remove As(III) through photocatalyic oxidation and adsorption. With a saturation magnetization of 27.39 emu/g, ZrO 2 -Fe 3 O 4 nanoparticles with size of 10–30 nm could be easily separated from solutions with a simple magnetic process. Under UV light, As(III) could be completely oxidized to less toxic As(V) by ZrO 2 -Fe 3 O 4 nanoparticles within 40 min in the photocatalytic reaction. Simultaneously, As(V) could be adsorbed onto the surface of nanoparticles with high efficiency. The adsorption of As(V) was well fitted by the pseudo-second-order model and the Freundlich isotherm model, respectively, and the maximum adsorption capacities of the nanoparticles was 133.48 mg/g at pH 7.0. As(III) could be effectively removed by ZrO 2 -Fe 3 O 4 nanoparticles at initial pH range from 4 to 8. Among all the common coexisting ions investigated, except for chloride and sulfate, carbonate, silicate and phosphate decreased the As(III) removal by competing with arsenic species for adsorption sites. The synthesized magnetic ZrO 2 -Fe 3 O 4 combined the photocatalytic oxidation property of ZrO 2 and the high adsorption capacity of both ZrO 2 and Fe 3 O 4 , which make it have significant potential applications in the As(III)-contaminated water treatment." @default.
- W2607383940 created "2017-04-28" @default.
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- W2607383940 date "2017-09-01" @default.
- W2607383940 modified "2023-09-22" @default.
- W2607383940 title "Efficient removal of arsenite through photocatalytic oxidation and adsorption by ZrO 2 -Fe 3 O 4 magnetic nanoparticles" @default.
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- W2607383940 doi "https://doi.org/10.1016/j.apsusc.2017.04.137" @default.
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