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• W2607388666 startingPage "4866" @default.
• W2607388666 abstract "We report the first synthesis of norbornyl-bridged acene dimers (2 and 3) with well-defined and controlled spatial relationships between the acene chromophore subunits. We employ a modular 2-D strategy wherein the central module, common to all our compounds, is a norbornyl moiety. The acenes are attached to this module using the Diels-Alder reaction, which also forms one of the acene rings. Manipulation of the Diels-Alder adducts provides the desired geometrically defined bis-acenes. The modular nature of this synthesis affords flexibility and allows for the preparation of a variety of acene dimers, including functionalized tetracene dimers." @default.
• W2607388666 created "2017-04-28" @default.
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• W2607388666 date "2017-04-21" @default.
• W2607388666 modified "2023-09-29" @default.
• W2607388666 title "Synthesis of Geometrically Well-Defined Covalent Acene Dimers for Mechanistic Exploration of Singlet Fission" @default.
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• W2607388666 doi "https://doi.org/10.1021/acs.joc.7b00602" @default.
• W2607388666 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28394594" @default.
• W2607388666 hasPublicationYear "2017" @default.
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