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• W2607506280 abstract "A series of PdNi/SiO2 bimetallic nanoparticles were synthesized using polyvinylpyrrolidone (PVP) and 2,6-bis(5,6-dimethyl-1,2,4-triazine-3-yl) pyridine (BTP) as ligands through sol-gel method. BTP was proved to be an effective ligand that can delay the reduction of palladium (II), which helps the formation of palladium-rich shell bimetallic nanoparticles. Pd3Ni7-BTP/SiO2 exhibited the best catalytic performance (TOF = 180 h− 1) among all the catalysts for hydrogenation of nitrobenzene under ambient conditions and was successfully reused for at least five times without loss in activity. The excellent catalytic performance could be ascribed to the small nanoparticle size (2.14 nm) and the palladium-rich shell structure it bears." @default.
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• W2607506280 date "2017-07-01" @default.
• W2607506280 modified "2023-10-15" @default.
• W2607506280 title "Ligand-controlled fabrication of core-shell PdNi bimetallic nanoparticles as a highly efficient hydrogenation catalyst" @default.
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• W2607506280 doi "https://doi.org/10.1016/j.catcom.2017.04.025" @default.
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