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- W2607516482 abstract "In order to dimethyl carbonate generated from methyl carbamate and methanol, several mixed oxide catalysts were prepared by coprecipitation during the batch stage, the DMC yield was adjusted to below 35 %. A fixed‐bed reactor was designed in order to minimize the unfavorable thermodynamic equilibrium and side reactions for generation. Results indicate that a maximum DMC yield of ∼ 73 % could be realized over a ZnO‐Al2O3 catalyst. In this process,the effects of reaction conditions for this type of reactor were investigated in detail. The catalytic performance of a ZnO‐Al2O3 catalyst for dimethyl carbonate generation from methyl carbamate and methanol in a fixed‐bed reactor was evaluated. With this method, DMC could be effectively synthesized by stripping off NH3 from the reaction zone which simultaneously minimized the side reactions." @default.
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- W2607516482 date "2013-01-01" @default.
- W2607516482 modified "2023-09-26" @default.
- W2607516482 title "Generating Dimethyl Carbonate: an approaching using Fixed‐Bed Reactor" @default.
- W2607516482 hasPublicationYear "2013" @default.
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