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- W2607777178 abstract "The title compound, C 22 H 34 O 6 , is a product of oxidation of squalene with the catalytic system RuO 4 (cat.)/NaIO 4 . The asymmetric unit contains two crystallographically independent molecules of very similar geometry approximately related by the non-crystallographic translation vector c /2. As a consequence, the average diffracted intensity in the hkl layers with odd l is systematically lower than in the layers with even l . In one molecule, the lactone ring and part of the adjacent tetrahydrofuran ring are disordered over two orientations with refined occupancy ratio of 0.831 (10):0.169 (10). The crystal structure is mainly governed by van der Waals forces." @default.
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- W2607777178 date "2017-04-28" @default.
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- W2607777178 title "Crystal structure of a new spiro-polytetrahydrofuran compound with translational pseudosymmetry:rac-(2S,2′S,5′R)-2-methyl-5′-[(1R,2R,5S,5′R)-1,4,4,5′-tetramethyldihydro-3′H-3,8-dioxaspiro[bicyclo[3.2.1]octane-2,2′-furan]-5′-yl]hexahydro[2,2′-bifuran]-5(2H)-one" @default.
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- W2607777178 doi "https://doi.org/10.1107/s2056989017006065" @default.
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