Matches in SemOpenAlex for { <https://semopenalex.org/work/W2608165712> ?p ?o ?g. }
- W2608165712 endingPage "9271" @default.
- W2608165712 startingPage "9266" @default.
- W2608165712 abstract "The activity of the water reduction catalyst [CoIII (L1 )(pyr)2 ]PF6 (1), where (L1 )2- is a bis-amido pyridine ligand and pyr is pyrrolidine, is investigated. Catalyst 1 has an overpotential of 0.54 V and a high observed TOF of 23 min-1 , albeit for a relatively short time. Considering the significant activity of 1 and aiming to improve catalyst design, a detailed structural and electronic study is performed to understand the mechanisms of deactivation. Experimental and theoretical evidence support that the metal-reduced [CoI (L1 )]- is in tautomeric equilibrium with the ligand-reduced [CoII (L1. )]- species. While [CoI (L1 )]- favors formation of a CoIII -H- relevant for catalysis, the [CoII (L1. )]- species leads to ligand protonation, structural distortions, and, ultimatley, catalyst deactivation." @default.
- W2608165712 created "2017-05-05" @default.
- W2608165712 creator A5032282584 @default.
- W2608165712 creator A5033107754 @default.
- W2608165712 creator A5040412768 @default.
- W2608165712 creator A5072645125 @default.
- W2608165712 date "2017-05-22" @default.
- W2608165712 modified "2023-09-25" @default.
- W2608165712 title "Deactivation of a Cobalt Catalyst for Water Reduction through Valence Tautomerism" @default.
- W2608165712 cites W1966792574 @default.
- W2608165712 cites W1967244854 @default.
- W2608165712 cites W1969073248 @default.
- W2608165712 cites W1986431620 @default.
- W2608165712 cites W1989205080 @default.
- W2608165712 cites W1989854295 @default.
- W2608165712 cites W1993483396 @default.
- W2608165712 cites W1996733738 @default.
- W2608165712 cites W2002501551 @default.
- W2608165712 cites W2005588293 @default.
- W2608165712 cites W2008032608 @default.
- W2608165712 cites W2008628004 @default.
- W2608165712 cites W2011215428 @default.
- W2608165712 cites W2017970618 @default.
- W2608165712 cites W2025054009 @default.
- W2608165712 cites W2032498497 @default.
- W2608165712 cites W2033990154 @default.
- W2608165712 cites W2037332368 @default.
- W2608165712 cites W2037529462 @default.
- W2608165712 cites W2047677444 @default.
- W2608165712 cites W2047853910 @default.
- W2608165712 cites W2048451151 @default.
- W2608165712 cites W2048813202 @default.
- W2608165712 cites W2058398316 @default.
- W2608165712 cites W2059508905 @default.
- W2608165712 cites W2063663126 @default.
- W2608165712 cites W2063765458 @default.
- W2608165712 cites W2065843750 @default.
- W2608165712 cites W2065868150 @default.
- W2608165712 cites W2070365441 @default.
- W2608165712 cites W2094642658 @default.
- W2608165712 cites W2096751623 @default.
- W2608165712 cites W2105249240 @default.
- W2608165712 cites W2132236427 @default.
- W2608165712 cites W2138503485 @default.
- W2608165712 cites W2142671255 @default.
- W2608165712 cites W2148911913 @default.
- W2608165712 cites W2157116861 @default.
- W2608165712 cites W2157932918 @default.
- W2608165712 cites W2166604647 @default.
- W2608165712 cites W2191887730 @default.
- W2608165712 cites W2215265600 @default.
- W2608165712 cites W2253358655 @default.
- W2608165712 cites W2313709827 @default.
- W2608165712 cites W2314550610 @default.
- W2608165712 cites W2316616988 @default.
- W2608165712 cites W2316785992 @default.
- W2608165712 cites W2325461376 @default.
- W2608165712 cites W2335076995 @default.
- W2608165712 cites W2340172419 @default.
- W2608165712 cites W2345472740 @default.
- W2608165712 cites W2533073630 @default.
- W2608165712 cites W4234399958 @default.
- W2608165712 cites W4237687167 @default.
- W2608165712 cites W4240661006 @default.
- W2608165712 cites W4244130890 @default.
- W2608165712 cites W4244417843 @default.
- W2608165712 cites W4249595546 @default.
- W2608165712 doi "https://doi.org/10.1002/chem.201701783" @default.
- W2608165712 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28437020" @default.
- W2608165712 hasPublicationYear "2017" @default.
- W2608165712 type Work @default.
- W2608165712 sameAs 2608165712 @default.
- W2608165712 citedByCount "13" @default.
- W2608165712 countsByYear W26081657122018 @default.
- W2608165712 countsByYear W26081657122019 @default.
- W2608165712 countsByYear W26081657122020 @default.
- W2608165712 countsByYear W26081657122021 @default.
- W2608165712 countsByYear W26081657122022 @default.
- W2608165712 countsByYear W26081657122023 @default.
- W2608165712 crossrefType "journal-article" @default.
- W2608165712 hasAuthorship W2608165712A5032282584 @default.
- W2608165712 hasAuthorship W2608165712A5033107754 @default.
- W2608165712 hasAuthorship W2608165712A5040412768 @default.
- W2608165712 hasAuthorship W2608165712A5072645125 @default.
- W2608165712 hasBestOaLocation W26081657123 @default.
- W2608165712 hasConcept C111233374 @default.
- W2608165712 hasConcept C116569031 @default.
- W2608165712 hasConcept C145148216 @default.
- W2608165712 hasConcept C147789679 @default.
- W2608165712 hasConcept C155647269 @default.
- W2608165712 hasConcept C161790260 @default.
- W2608165712 hasConcept C168900304 @default.
- W2608165712 hasConcept C170493617 @default.
- W2608165712 hasConcept C17525397 @default.
- W2608165712 hasConcept C178790620 @default.
- W2608165712 hasConcept C179104552 @default.
- W2608165712 hasConcept C185592680 @default.
- W2608165712 hasConcept C186460083 @default.