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- W2608512952 abstract "The asymmetric unit of the hydrated title salt, (C 10 H 28 N 4 )[Cr 2 O 7 ] 2 ·H 2 O [C 10 H 28 N 4 = H 4 (cyclam) = 1,4,8,11-tetraazoniacyclotetradecane], contains two half-cations (both completed by crystallographic inversion symmetry), two dichromate anions and one water molecule. The two [CrO 7 ] 2− anions exhibit a nearly staggered conformation, with bridging angles of 133.37 (11) and 136.28 (12)°. The distortions of the dichromate anions are due to their participation in hydrogen-bonding interactions with the water molecule and the cations. Intermolecular hydrogen bonds involving the cyclam N—H groups and water O—H groups as donor groups, and the O atoms of the dichromate anions as acceptor groups give rise to a three-dimensional network." @default.
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- W2608512952 date "2017-04-28" @default.
- W2608512952 modified "2023-10-13" @default.
- W2608512952 title "Crystal structure of 1,4,8,11-tetraazoniacyclotetradecane bis(dichromate) monohydrate from synchrotron data" @default.
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- W2608512952 doi "https://doi.org/10.1107/s2056989017005771" @default.
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