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- W2608667462 abstract "Abstract A dual temperature‐ and light‐responsive C 2 H 2 /C 2 H 4 separation switch in a diarylethene metal–organic framework (MOF) is presented. At 195 K and 100 kPa this MOF shows ultrahigh C 2 H 2 /C 2 H 4 selectivity of 47.1, which is almost 21.4 times larger than the corresponding value of 2.2 at 293 K and 100 kPa, or 15.7 times larger than the value of 3.0 for the material under UV at 195 K and 100 kPa. The origin of this unique control in C 2 H 2 /C 2 H 4 selectivity, as unveiled by density functional calculations, is due to a guest discriminatory gate‐opening effect from the diarylethene unit." @default.
- W2608667462 created "2017-05-05" @default.
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- W2608667462 date "2017-04-24" @default.
- W2608667462 modified "2023-10-09" @default.
- W2608667462 title "Significant Enhancement of C<sub>2</sub> H<sub>2</sub> /C<sub>2</sub> H<sub>4</sub> Separation by a Photochromic Diarylethene Unit: A Temperature- and Light-Responsive Separation Switch" @default.
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- W2608667462 doi "https://doi.org/10.1002/anie.201702484" @default.
- W2608667462 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28436067" @default.
- W2608667462 hasPublicationYear "2017" @default.