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- W2609135383 abstract "BaTiO3 was prepared by co-precipitation method and BaTiF6 was synthesized by wet impregnation method using BaTiO3 as the precursor. The phase structure of BaTiO3 and BaTiF6 were characterized by PXRD and the results confirmed the pure tetragonal phase for BaTiO3 and a slightly distorted rhombohedral structure for BaTiF6. The calculated values of tolerance factor confirms the successful replacement of oxygen ion by fluorine ion in the BaTiO3 lattice. BaTiF6 showed an extended absorbance in the visible region compared to BaTiO3 and their band gap energy values were found to be 2.91 and 3.03 eV respectively. FTIR studies confirmed the presence of F in BaTiF6 and the F-Ti-F stretching modes are observed in the region of 450–600 cm−1. SEM images of BaTiF6 showed the formation of fibrous hair-like morphology. The chemical environment and elemental binding states of Ba, Ti, O and F were confirmed by XPS analysis. BET analysis showed that BaTiF6 had higher surface area compared to BaTiO3. The mode of charge carrier recombination mechanism of each photocatalyst was studied by the PL technique. The better photocatalytic performance of BaTiF6 under UV/solar light is discussed in detail." @default.
- W2609135383 created "2017-05-05" @default.
- W2609135383 creator A5008747926 @default.
- W2609135383 creator A5084936702 @default.
- W2609135383 date "2018-06-01" @default.
- W2609135383 modified "2023-09-30" @default.
- W2609135383 title "Preparation, characterization and photocatalytic activity of BaTiF 6 and BaTiO 3 : A comparative study" @default.
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- W2609135383 doi "https://doi.org/10.1016/j.jece.2017.04.038" @default.
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