Matches in SemOpenAlex for { <https://semopenalex.org/work/W2609178712> ?p ?o ?g. }
- W2609178712 endingPage "11487" @default.
- W2609178712 startingPage "11472" @default.
- W2609178712 abstract "The surface saturation of solutions of three low molecular weight surface-active alcohols was identified independently of bulk solution using sum frequency generation spectroscopy. Tensiometry showed that the solution surface tension kept decreasing uniformly and considerably, even after full saturation of the adsorption monolayer. We employed Guggenheim’s model of the extended interface to attribute this observation to the ongoing adsorption of alcohol molecules beneath the saturated topmost adsorption layer. Our investigation of the dynamic behavior of thin liquid films of the alcohol solutions revealed the tremendous effect of under-monolayer adsorption on the rheological characteristics of the surface. The under-monolayer region was found to function as a supplementary source of alcohol molecules. The fast diffusion of surfactants from the under-monolayer region to the topmost adsorption layer imposed a buffering effect on the dynamic response of the surface through diminishing the surface tension gradient created by the surface expansion. This resulted in a sudden drop of the surface elasticity and consequently a faster-decaying foam. While equilibrium surface tension does not distinguish between the monolayer and the under-monolayer, the dynamic properties of a fluid surface seem to be sensitive to the adsorption geometry." @default.
- W2609178712 created "2017-05-05" @default.
- W2609178712 creator A5014218616 @default.
- W2609178712 creator A5025770861 @default.
- W2609178712 creator A5035163179 @default.
- W2609178712 creator A5045997633 @default.
- W2609178712 creator A5052237120 @default.
- W2609178712 creator A5086419816 @default.
- W2609178712 date "2017-05-11" @default.
- W2609178712 modified "2023-10-14" @default.
- W2609178712 title "Effect of Under-Monolayer Adsorption on Foamability, Rheological Characteristics, and Dynamic Behavior of Fluid Interfaces: Experimental Evidence for the Guggenheim Extended Interface Model" @default.
- W2609178712 cites W1964667007 @default.
- W2609178712 cites W1965306364 @default.
- W2609178712 cites W1969421181 @default.
- W2609178712 cites W1970805130 @default.
- W2609178712 cites W1973482687 @default.
- W2609178712 cites W1983163915 @default.
- W2609178712 cites W1985668795 @default.
- W2609178712 cites W1986113254 @default.
- W2609178712 cites W1986273614 @default.
- W2609178712 cites W1990163562 @default.
- W2609178712 cites W1996883801 @default.
- W2609178712 cites W1997544557 @default.
- W2609178712 cites W2009234269 @default.
- W2609178712 cites W2011702007 @default.
- W2609178712 cites W2013107255 @default.
- W2609178712 cites W2013545186 @default.
- W2609178712 cites W2013703493 @default.
- W2609178712 cites W2016194029 @default.
- W2609178712 cites W2024339515 @default.
- W2609178712 cites W2024547608 @default.
- W2609178712 cites W2025641820 @default.
- W2609178712 cites W2027551773 @default.
- W2609178712 cites W2029046066 @default.
- W2609178712 cites W2030635479 @default.
- W2609178712 cites W2032778255 @default.
- W2609178712 cites W2035633565 @default.
- W2609178712 cites W2036270919 @default.
- W2609178712 cites W2038462014 @default.
- W2609178712 cites W2041132702 @default.
- W2609178712 cites W2042142209 @default.
- W2609178712 cites W2049682985 @default.
- W2609178712 cites W2051861652 @default.
- W2609178712 cites W2055632243 @default.
- W2609178712 cites W2056433905 @default.
- W2609178712 cites W2065900671 @default.
- W2609178712 cites W2066506561 @default.
- W2609178712 cites W2066512277 @default.
- W2609178712 cites W2067954344 @default.
- W2609178712 cites W2068053572 @default.
- W2609178712 cites W2071815243 @default.
- W2609178712 cites W2085965591 @default.
- W2609178712 cites W2088263336 @default.
- W2609178712 cites W2089260408 @default.
- W2609178712 cites W2093535471 @default.
- W2609178712 cites W2106428403 @default.
- W2609178712 cites W2114803374 @default.
- W2609178712 cites W2116570706 @default.
- W2609178712 cites W2130584511 @default.
- W2609178712 cites W2137419733 @default.
- W2609178712 cites W2140160144 @default.
- W2609178712 cites W2145634709 @default.
- W2609178712 cites W2163948969 @default.
- W2609178712 cites W2167671971 @default.
- W2609178712 cites W2176835500 @default.
- W2609178712 cites W2270276037 @default.
- W2609178712 cites W2318864839 @default.
- W2609178712 cites W2323362998 @default.
- W2609178712 cites W2327987071 @default.
- W2609178712 cites W2503743381 @default.
- W2609178712 cites W2534858438 @default.
- W2609178712 cites W2608029284 @default.
- W2609178712 cites W2610097080 @default.
- W2609178712 cites W2610428191 @default.
- W2609178712 cites W2611783303 @default.
- W2609178712 cites W2611824482 @default.
- W2609178712 cites W3190700223 @default.
- W2609178712 cites W4298386547 @default.
- W2609178712 doi "https://doi.org/10.1021/acs.jpcc.7b02483" @default.
- W2609178712 hasPublicationYear "2017" @default.
- W2609178712 type Work @default.
- W2609178712 sameAs 2609178712 @default.
- W2609178712 citedByCount "15" @default.
- W2609178712 countsByYear W26091787122018 @default.
- W2609178712 countsByYear W26091787122019 @default.
- W2609178712 countsByYear W26091787122020 @default.
- W2609178712 countsByYear W26091787122021 @default.
- W2609178712 countsByYear W26091787122022 @default.
- W2609178712 countsByYear W26091787122023 @default.
- W2609178712 crossrefType "journal-article" @default.
- W2609178712 hasAuthorship W2609178712A5014218616 @default.
- W2609178712 hasAuthorship W2609178712A5025770861 @default.
- W2609178712 hasAuthorship W2609178712A5035163179 @default.
- W2609178712 hasAuthorship W2609178712A5045997633 @default.
- W2609178712 hasAuthorship W2609178712A5052237120 @default.
- W2609178712 hasAuthorship W2609178712A5086419816 @default.
- W2609178712 hasBestOaLocation W26091787122 @default.
- W2609178712 hasConcept C114614502 @default.