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- W2609405774 abstract "A triad of d10 cobalt dihydrogen complexes was synthesized by utilizing Lewis acidic group 13 metalloligands, M[N((o-C6H4)NCH2PiPr2)3], where M = Al, Ga, and In. These complexes have formal Co(−I) oxidation states, representing the only coordination complexes in which dihydrogen is bound to a subvalent transition metal center. Single-crystal X-ray diffraction and NMR studies support the assignment of these complexes as nonclassical dihydrogen adducts of Co(−I)." @default.
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- W2609405774 date "2017-05-04" @default.
- W2609405774 modified "2023-10-16" @default.
- W2609405774 title "Stable Dihydrogen Complexes of Cobalt(−I) Suggest an Inverse <i>trans</i>-Influence of Lewis Acidic Group 13 Metalloligands" @default.
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- W2609405774 doi "https://doi.org/10.1021/jacs.7b02870" @default.
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