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- W2609543801 abstract "The first example of a photoexcitated amine-catalyzed process for asymmetric Michael addition of o-quinodimethanes to enones is described. In the presence of simple chiral amino acid esters, a variety of Michael adducts were generally obtained in good yields and excellent stereoselectivities. This strategy can be successfully applied to 3-substituted-2-cyclohexenones and provides an asymmetric access to all-carbon quaternary centers. Furthermore, the high stereocontrol was explained by means of density-functional theory (DFT) calculations." @default.
- W2609543801 created "2017-05-05" @default.
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- W2609543801 date "2017-04-26" @default.
- W2609543801 modified "2023-10-17" @default.
- W2609543801 title "Enantioselective Michael Addition of Photogenerated <i>o</i>-Quinodimethanes to Enones Catalyzed by Chiral Amino Acid Esters" @default.
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- W2609543801 doi "https://doi.org/10.1021/acs.orglett.7b00862" @default.
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