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- W2609798839 abstract "We dissected halogen-aryl π interactions experimentally using a bicyclic N-arylimide based molecular torsion balances system, which is based on the influence of the non-bonded interaction on the equilibria between folded and unfolded states. Through comparison of balances modulated by higher halogens with fluorine balances, we determined the magnitude of the halogen-aryl π interactions in our unimolecular systems to be larger than -5.0 kJ mol-1 , which is comparable with the magnitude estimated in the biomolecular systems. Our study provides direct experimental evidence of halogen-aryl π interactions in solution, which until now have only been revealed in the solid state and evaluated theoretically by quantum-mechanical calculations." @default.
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- W2609798839 date "2017-04-28" @default.
- W2609798839 modified "2023-09-30" @default.
- W2609798839 title "Direct Experimental Evidence for Halogen-Aryl π Interactions in Solution from Molecular Torsion Balances" @default.
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- W2609798839 doi "https://doi.org/10.1002/anie.201700520" @default.
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