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- W2609834884 endingPage "2159" @default.
- W2609834884 startingPage "2150" @default.
- W2609834884 abstract "Di- and trinuclear cobalt (Co)–salen complexes with a benzene ring as a rigid linker were explored for epoxide polymerizations. The dinuclear Co–salen complex with a 1,2-phenylene linker showed higher catalytic activity than the dinuclear Co–salen complex with a 1,3-phenylene linker and the trinuclear Co–salen complex with a 1,3,5-benzenetriyl linker for the copolymerization of propylene oxide (PO) with carbon dioxide. A combination of the absolute configuration of the two Co–salen moieties was found to affect its catalytic activity. The optimized dinuclear Co–salen complex with a heterochiral combination demonstrated highest activity and maintained its catalytic activity under a low catalyst concentration. The heterochiral dinuclear Co–salen complex also showed high activity for the copolymerization of PO with cyclic anhydride. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2150–2159" @default.
- W2609834884 created "2017-05-05" @default.
- W2609834884 creator A5004626824 @default.
- W2609834884 creator A5064757729 @default.
- W2609834884 creator A5085595754 @default.
- W2609834884 date "2017-04-25" @default.
- W2609834884 modified "2023-10-18" @default.
- W2609834884 title "Multinuclear cobalt-salen complexes with phenylene linker for epoxide polymerizations" @default.
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