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• W2609841312 abstract "Abstract In the present study, TiO2 nanoparticles are used as inorganic nanofiller material to prepare nanocomposite proton exchange membrane (PEM). Sulfonated polyvinyl alcohol (SPVA) is synthesized by 4-formylbenzene-1,3-disulfonic acid disodium salt hydrate and water. The cross-linking reaction is performed by glutaraldehyde. These membranes were then dip coated with polyacrylic acid and chitosan alternately and one layer-by-layer (LBL), two LBL and three LBL membranes were prepared. The chemical structure evaluation of SPVA membrane is performed using FTIR. The direct methanol fuel cell (DMFC) catalysts of 10Cu/CeO2 and 10 Pt-10 CeO2/C were prepared by reduction reaction and hydrothermal technique. Thus obtained material was spin coated on 2 × 2 cm2 carbon paper to prepare catalyst anode/cathode. The morphology, size, and purity of catalyst particles are analysed by SEM, UV–visible spectroscopy, FTIR and EDS. Electrochemical analysis is also done to test the performance. Results show that Cu/CeO2 catalyst shows excellent catalysis towards methanol oxidation, which is better than 10 Pt-10 CeO2/C particles. The 10Cu/CeO2 catalyst gives peak voltage of 915 mV for infinite resistance, which is higher than the reported value of the conventional 20 Pt/C catalyst (810 mV)." @default.
• W2609841312 created "2017-05-05" @default.
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• W2609841312 date "2017-05-01" @default.
• W2609841312 modified "2023-09-27" @default.
• W2609841312 title "Enhanced performance of DMFC prepared by 10Cu/CeO 2 catalyst and nanocomposite SPVA membranes with layer-by-layer coating of polyacrylic acid and chitosan" @default.
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• W2609841312 doi "https://doi.org/10.1016/j.ijhydene.2017.04.008" @default.
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