FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2610227891> ?p ?o ?g. }

• W2610227891 endingPage "230" @default.
• W2610227891 startingPage "220" @default.
• W2610227891 abstract "The feasibility of an integrated continuous biphasic oxidation process was studied, incorporating (i) electrochemical generation of an oxidant, (ii) membrane emulsification and an Oscillatory Flow Reactor (OFR) to facilitate mass-transfer in a biphasic reaction system and (iii) product extraction to enable regeneration of the oxidant. The biphasic, organic solvent-free dihydroxylation of styrene by ammonium peroxodisulfate solutions (including electrochemically generated peroxodisulfate) was investigated as a model reaction, both in batch and in an OFR. Heating of peroxodisulfate in a strongly acidic solution was demonstrated to be essential to generate the active oxidant (Caro’s acid). Membrane emulsification allowed mass-transfer limitations to be overcome, reducing the time scale of styrene oxidation from several hours in a conventional stirred tank reactor to less than 50 min in a dispersion cell. The influence of droplet size on overall reaction rate in emulsions was studied in detail using fast image capturing technology. Generation of unstable emulsions was also demonstrated during the oxidation in OFR and product yields >70% were obtained. However, the high-frequency/high-displacement oscillations necessary for generation of fine droplets violated the plug flow regime. Membrane emulsification was successfully integrated with the OFR to perform biphasic oxidations. It was possible to operate the OFR/cross-flow membrane assembly in plug flow regime at some oscillatory conditions with comparable overall oxidation rates. No mass-transfer limitations were observed for droplets <60 μm. Finally, the continuous post-reaction separation was demonstrated in a single OFR extraction unit to enable continuous regeneration of the oxidant." @default.
• W2610227891 created "2017-05-12" @default.
• W2610227891 creator A5019713145 @default.
• W2610227891 creator A5027953390 @default.
• W2610227891 creator A5046274300 @default.
• W2610227891 creator A5048150379 @default.
• W2610227891 creator A5070381337 @default.
• W2610227891 creator A5076663906 @default.
• W2610227891 creator A5078005381 @default.
• W2610227891 date "2017-12-01" @default.
• W2610227891 modified "2023-10-14" @default.
• W2610227891 title "Controlled multiphase oxidations for continuous manufacturing of fine chemicals" @default.
• W2610227891 cites W1457414945 @default.
• W2610227891 cites W1969891604 @default.
• W2610227891 cites W2000256525 @default.
• W2610227891 cites W2006552184 @default.
• W2610227891 cites W2008327352 @default.
• W2610227891 cites W2028171168 @default.
• W2610227891 cites W2031622892 @default.
• W2610227891 cites W2037160264 @default.
• W2610227891 cites W2043892813 @default.
• W2610227891 cites W2045249622 @default.
• W2610227891 cites W2046480019 @default.
• W2610227891 cites W2065093837 @default.
• W2610227891 cites W2067234330 @default.
• W2610227891 cites W2073336250 @default.
• W2610227891 cites W2074179635 @default.
• W2610227891 cites W2082091698 @default.
• W2610227891 cites W2084654099 @default.
• W2610227891 cites W2085674398 @default.
• W2610227891 cites W2088570046 @default.
• W2610227891 cites W2106107041 @default.
• W2610227891 cites W2126363023 @default.
• W2610227891 cites W2139083301 @default.
• W2610227891 cites W2142495898 @default.
• W2610227891 cites W2147087276 @default.
• W2610227891 cites W2154859348 @default.
• W2610227891 cites W2183539766 @default.
• W2610227891 cites W21946501 @default.
• W2610227891 cites W2277398706 @default.
• W2610227891 cites W2321624414 @default.
• W2610227891 cites W2328207157 @default.
• W2610227891 cites W4239126688 @default.
• W2610227891 doi "https://doi.org/10.1016/j.cej.2017.05.017" @default.
• W2610227891 hasPublicationYear "2017" @default.
• W2610227891 type Work @default.
• W2610227891 sameAs 2610227891 @default.
• W2610227891 citedByCount "8" @default.
• W2610227891 countsByYear W26102278912017 @default.
• W2610227891 countsByYear W26102278912018 @default.
• W2610227891 countsByYear W26102278912019 @default.
• W2610227891 countsByYear W26102278912020 @default.
• W2610227891 countsByYear W26102278912022 @default.
• W2610227891 countsByYear W26102278912023 @default.
• W2610227891 crossrefType "journal-article" @default.
• W2610227891 hasAuthorship W2610227891A5019713145 @default.
• W2610227891 hasAuthorship W2610227891A5027953390 @default.
• W2610227891 hasAuthorship W2610227891A5046274300 @default.
• W2610227891 hasAuthorship W2610227891A5048150379 @default.
• W2610227891 hasAuthorship W2610227891A5070381337 @default.
• W2610227891 hasAuthorship W2610227891A5076663906 @default.
• W2610227891 hasAuthorship W2610227891A5078005381 @default.
• W2610227891 hasBestOaLocation W26102278911 @default.
• W2610227891 hasConcept C120665830 @default.
• W2610227891 hasConcept C121332964 @default.
• W2610227891 hasConcept C127413603 @default.
• W2610227891 hasConcept C147789679 @default.
• W2610227891 hasConcept C147831808 @default.
• W2610227891 hasConcept C15920480 @default.
• W2610227891 hasConcept C161790260 @default.
• W2610227891 hasConcept C172120300 @default.
• W2610227891 hasConcept C17352599 @default.
• W2610227891 hasConcept C177562468 @default.
• W2610227891 hasConcept C178790620 @default.
• W2610227891 hasConcept C179104552 @default.
• W2610227891 hasConcept C185592680 @default.
• W2610227891 hasConcept C191545125 @default.
• W2610227891 hasConcept C2777566558 @default.
• W2610227891 hasConcept C2780471494 @default.
• W2610227891 hasConcept C41625074 @default.
• W2610227891 hasConcept C42360764 @default.
• W2610227891 hasConcept C43617362 @default.
• W2610227891 hasConcept C4725764 @default.
• W2610227891 hasConcept C47502133 @default.
• W2610227891 hasConcept C51038369 @default.
• W2610227891 hasConcept C521977710 @default.
• W2610227891 hasConcept C55493867 @default.
• W2610227891 hasConcept C55904794 @default.
• W2610227891 hasConcept C67334161 @default.
• W2610227891 hasConcept C97355855 @default.
• W2610227891 hasConceptScore W2610227891C120665830 @default.
• W2610227891 hasConceptScore W2610227891C121332964 @default.
• W2610227891 hasConceptScore W2610227891C127413603 @default.
• W2610227891 hasConceptScore W2610227891C147789679 @default.
• W2610227891 hasConceptScore W2610227891C147831808 @default.
• W2610227891 hasConceptScore W2610227891C15920480 @default.
• W2610227891 hasConceptScore W2610227891C161790260 @default.
• W2610227891 hasConceptScore W2610227891C172120300 @default.

• next