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• W2610243816 abstract "Herein we describe concise enantioselective chemical syntheses of (-)-viridin and (-)-viridiol. Our convergent approach couples two achiral fragments of similar complexity and employs an enantioselective intramolecular Heck reaction to set the absolute stereochemical configuration of an all-carbon quaternary stereocenter. To complete the syntheses of these base- and nucleophile-sensitive natural products, we conduct carefully orchestrated site- and diastereoselective oxidations and other transformations. Our work is the first to generate these targets as single enantiomers." @default.
• W2610243816 created "2017-05-12" @default.
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• W2610243816 date "2017-05-12" @default.
• W2610243816 modified "2023-10-16" @default.
• W2610243816 title "Enantioselective Chemical Syntheses of the Furanosteroids (−)-Viridin and (−)-Viridiol" @default.
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• W2610243816 doi "https://doi.org/10.1021/jacs.7b02829" @default.
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