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- W2610341741 abstract "We have developed a copper-catalyzed enantioselective intermolecular aminoarylation of alkenes using a novel N-fluoro-N-alkylsulfonamide as the amine reagent, which could react with the Cu(I) catalyst to release a related amino radical. After addition to styrene, the generated benzylic radical could couple with a chiral L*CuIIAr complex to achieve enantioselective arylation. Various optical 2,2-diarylethylamines were efficiently synthesized from simple styrenes with high enantioselectivity, and these products can serve as valuable synthons toward bioactive molecules' synthesis." @default.
- W2610341741 created "2017-05-12" @default.
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- W2610341741 date "2017-05-10" @default.
- W2610341741 modified "2023-10-17" @default.
- W2610341741 title "Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines" @default.
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- W2610341741 doi "https://doi.org/10.1021/jacs.7b02455" @default.
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