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- W2610486614 abstract "Novel double perovskite Li2MgZrO4:Mn4+(LMZ:Mn4+) phosphor is prepared by high-temperature solid-state reaction method in air. Excitation bands peaking at ~335, 395, and 482 nm of LMZ:Mn4+ phosphor in the range of 220–600 nm are attributed to the O2-–Mn4+ charge transfer and the 4A2→4T1, 2T2, and 4T2 transitions of Mn4+ ion, respectively. Emission band peaking at ~670 nm of LMZ:Mn4+ phosphor within the range 610–790 nm is assigned to the 2E→4A2 transition of Mn4+ ion with host lattice vibration, which indicate that LMZ:Mn4+ phosphor has an application prospect in the red light-emitting diodes for plant growth. The optimal Mn4+ ion concentration in LMZ:Mn4+ phosphor is ~0.4 mol%. Fluorescence lifetime and quantum efficiency of LMZ:0.4%Mn4+ phosphor are ~251.47 μs and 32.3% at room temperature, respectively. The influence of temperature to luminescence properties is explained by the schematic configuration coordinate diagram. The luminous mechanism is explained by the energy level diagram of Mn4+." @default.
- W2610486614 created "2017-05-12" @default.
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- W2610486614 date "2017-08-01" @default.
- W2610486614 modified "2023-10-14" @default.
- W2610486614 title "Preparation and luminescence properties of Li 2 MgZrO 4 :Mn 4+ red phosphor for plant growth" @default.
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- W2610486614 doi "https://doi.org/10.1016/j.jlumin.2017.05.002" @default.
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