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• W2610588593 abstract "Bis(2-pyridyl)diselenoether with the general formula (2-PySe)2(CH2) (L) reacts with Ph3PAuCl and [(dpph)(AuCl)2] dpph = 1,6-bis(diphenylphosphino)hexane to produce the respective complexes [(L)Au2(PPh3)2](PF6)2 (1) and [(L)(dpph)Au2(PF6)2]n (2). These complexes were isolated in crystalline form and studied using spectroscopic and X-ray diffraction techniques. The coordination of the ligand (2-PySe)2(CH2) (L) to the gold(I) metal centers in complexes [(L)Au2(PPh3)2](PF6)2 (1) and [(L)(dpph)Au2(PF6)2]n (2) occurs via the nitrogen atom of the pyridine ring, with no interaction with the selenium atoms of the bis(2-pyridyl)diselenoether. The gold derivative (Ph3PAuCl or [(dpph)(AuCl)2]) is responsible for the formation of a molecular complex (1) or a polymeric complex (2), and in both compounds the gold(I) metal atoms adopt an almost linear geometry." @default.
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• W2610588593 date "2017-07-01" @default.
• W2610588593 modified "2023-09-26" @default.
• W2610588593 title "Gold(I) phosphine complexes with bis(2-pyridyl)diselenoether: Synthesis and structure elucidation" @default.
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• W2610588593 doi "https://doi.org/10.1016/j.inoche.2017.05.002" @default.
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