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• W2610620649 abstract "Abstract Zinc tungstate (ZnWO 4 ) nanomaterials with cubic and other morphologies had been prepared by utilizing a simple microwave heating route within 250 s followed by subsequent annealing for 2 h by the reaction of Zn(II) salt solution with CTAB surfactant in presence of sodium tungstate for the first time. The reaction sensitively generated ZnWO 4 nanomaterials with different morphologies just by tuning the reaction parameters. The average length of the side of ZnWO 4 cubes is 68 ± 14 nm. These ZnWO 4 nanomaterials were utilized as an excellent catalyst material for the catalytic reduction of [K 3 Fe(CN) 6 ] to [K 4 Fe(CN) 6 ] in presence of sodium thiosulphate and also for the degradation of toxic organic dye molecules from water by UV irradiation. For catalytic reduction, the conversion of [K 3 Fe(CN) 6 ] to [K 4 Fe(CN) 6 ] using ZnWO 4 as catalyst was faster and completed within an hour. This was the first ever report of [K 3 Fe(CN) 6 ] reduction using ZnWO 4 as catalyst and observed highest catalytic rate ever reported for similar class of catalyst materials. For dye degradation study, the degradation of two cationic dyes such as rhodamine B (RhB), methylene blue (MB) and two anionic dyes such as Rose Bengal (RB) and fluorescein in presence of ZnWO 4 as catalyst under UV light irradiation were studied. The highest catalytic rate was found with a minimum catalyst loading. The catalytic rate was found high in case of anionic dyes compared to cationic dyes. The order of their degradation follows as: fluorescein > RB > MB > RhB. A brief mechanism for the photocatalytic dye degradation is elaborated. Other than catalysis, the synthesized ZnWO 4 nanomaterials can also be suitable in other important applications such as luminescence studies and different energy related applications." @default.
• W2610620649 created "2017-05-12" @default.
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• W2610620649 date "2017-09-01" @default.
• W2610620649 modified "2023-09-29" @default.
• W2610620649 title "Microwave assisted swift synthesis of ZnWO 4 nanomaterials: material for enhanced photo-catalytic activity" @default.
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• W2610620649 doi "https://doi.org/10.1016/j.jphotochem.2017.05.004" @default.
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