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- W2610757788 abstract "Abstract The ability to selectively form one crystal structure among several options in a polymorphic system is an important goal in solid‐state synthesis. Nanocrystal cation exchange, which proceeds rapidly under mild conditions, can retain key structural features and yield otherwise inaccessible phases, but the extent to which crystal structure can be retained and therefore selectively targeted during such reactions has been limited. Here, we show that nanocrystals of digenite Cu 2−x S transform to zincblende MnS and CoS upon cation exchange. Zincblende MnS and CoS, which are metastable in bulk, retain both the tetrahedral cation coordination and cubic close packed anion sublattice of digenite Cu 2−x S. Comparison with wurtzite MnS and CoS, which have been accessed previously through analogous cation exchange of roxbyite Cu 2−x S, demonstrates the selective formation of the related zincblende vs. wurtzite polymorphs by cation exchange of structurally distinct templates." @default.
- W2610757788 created "2017-05-12" @default.
- W2610757788 creator A5041204959 @default.
- W2610757788 creator A5068518417 @default.
- W2610757788 date "2017-05-02" @default.
- W2610757788 modified "2023-10-11" @default.
- W2610757788 title "Structure‐Selective Cation Exchange in the Synthesis of Zincblende MnS and CoS Nanocrystals" @default.
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- W2610757788 doi "https://doi.org/10.1002/anie.201701087" @default.
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