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- W2610776658 abstract "The first cinchona-alkaloid-organocatalyzed enantioselective synthesis of chiral 1,4-dihydropyridine derivatives is described. Bis-cinchona catalyst 3b activates the Michael addition reaction between malononitrile derivatives 2 and enamines 1, affording the appealing and highly substituted 1,4-dihydropyridines 4 with very good results in most cases. This is one of very few examples of the synthesis of chiral 1,4-dihydropyridines by an enantioselective catalytic procedure. The highly substituted final compounds are of interest for their potential biological activity. This efficient protocol opens the door to a new area of research for the asymmetric construction of these skeletons for which enantioselective syntheses are still very limited." @default.
- W2610776658 created "2017-05-12" @default.
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- W2610776658 date "2017-05-18" @default.
- W2610776658 modified "2023-10-13" @default.
- W2610776658 title "Asymmetric Organocatalytic Synthesis of Substituted Chiral 1,4-Dihydropyridine Derivatives" @default.
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- W2610776658 doi "https://doi.org/10.1021/acs.joc.7b00176" @default.
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